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Mining activity in the county included ores of lead, copper, zinc, and deposits of refractory clay.The soils in most of the county tend to be thin, rocky red clay, and are poor for most agriculture, while the soil near the Missouri River is dark, rich, and thick, and used primarily for row crops such as corn, wheat, and soybeans.The racial makeup of the county was 97.47% White, 0.94% Black or African American, 0.27% Asian, 0.24% Native American, 0.02% Pacific Islander, 0.20% from other races, and 0.86% from two or more races.Approximately 0.72% of the population were Hispanic or Latino of any race.For the next two decades, most settlers came from the Upper South, especially Kentucky and Virginia, bringing their slaves with them to work the land.In 1833 substantial numbers of German immigrant families began settling in the area, and soon they outnumbered the slave owners in the county. Former governor and then Confederate General Sterling Price led his cavalry though the county during his Missouri raid of 1864.The county has wineries that are included in the Hermann AVA (American Viticultural Area) and is part of the region known as the Missouri Rhineland, which extends on both sides of the Missouri River.Occupied by succeeding cultures of indigenous peoples, this area was populated by the historic Osage tribe at the time of European encounter.

There were 34,945 households out of which 36.10% had children under the age of 18 living with them, 60.40% were married couples living together, 9.00% had a female householder with no husband present, and 26.50% were non-families.

Röbller Vineyard and Winery near New Haven is also in the Hermann AVA.

Wineries along both sides of the Missouri River are part of the Missouri Rhineland, whose vineyards were started by German immigrants in the mid-19th century.

Louis, MO-IL Metropolitan Statistical Area and contains many of the city's exurbs.

It is located along the south side of the Missouri River.

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